1,3-Bis[(−)-(S)-(1-phenylethyl)iminomethyl]benzene
نویسندگان
چکیده
منابع مشابه
1,3-Bis[(−)-(S)-(1-phenylethyl)iminomethyl]benzene
The title compound, C(24)H(24)N(2), is an enanti-omerically pure bis-aldimine, which displays twofold crystallographic symmetry, with two C atoms of the central benzene ring lying on the symmetry axis. The imine group is slightly twisted from the benzene core, with a dihedral angle of 12.72 (16)° between the benzene ring and the C=N-C(*) plane. The terminal phenyl rings make an angle of 66.44 (...
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The title complex, [Fe2(C5H5)2(C18H20O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C-O-C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows a staggered conformation whereas the other shows an eclipsed conformation.
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The title compound, C(32)H(28)N(2), is a chiral bis-imine in which both imine groups display the common E configuration. The naphthyl groups present different orientations with respect to the central core, as reflected in the dihedral angles of 21.4 (2) and 78.83 (14)° between the benzene and naphthyl mean planes, thus the highest possible C(2) local molecular symmetry is not attained. This C(1...
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The title mol-ecule, C(26)H(24)N(2)O(2), displays C(2) symmetry, with the mol-ecule located on a twofold axis perpendicular to the plane of the oxalamide unit -NH-CO-CO-NH-. The oxalamide core deviates from planarity, as reflected by the O=C-C=O and N-C-C-N torsion angles of 164.3 (5) and 163.2 (5)°, respectively. The naphthyl groups are oriented toward the same face of the oxalamide mean plane...
متن کاملBis(ferrocenecarbaldehyde thiosemicarbazonato-κ2 N 1,S)zinc
In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(7)H(7)N(3)S)(2)], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thio-semicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetra-hedral environment. N-H⋯S, N-H⋯N, C-H⋯S and C-H⋯N intra- and intermol-ecular inter-actions connect the mol-ecules i...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811021556